H 2 O dissolved in tricresyl phosphate TCP as pasting liquid were prepared. The modified electrodes showed Nernstian slopes of The selectivity coefficients for mono-, di-, and trivalent cations indicate the good selectivity of sensor for Cu I and Cu II ions over a large number of interfering cations. As a result the proposed electrodes were applied to Cu I and Cu II ions determination in mixture solutions, wastewater samples. Elemental analysis, magnetic susceptibility measurements, molar conductance, thermal analysis and spectroscopic techniques has been used for characterization and elucidation for the structure the isolated materials. C 2 H 5 OH shows diamagnetic moment which may be arising from anodic dissolution of Cu I during the electrolysis of Copper metal during electrochemical preparation.
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Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids ILs and deep eutectic solvents, thus, have been paid great attention to replace current harsh organic solvents and have been applied to many chemical processing such as extraction and synthesis. However, current ionic liquids and deep eutectic solvents have still limitations to be applied to a real chemical industry due to toxicity against human and environment and high cost of ILs and solid state of most deep eutectic solvents at room temperature. Recently we discovered that many plant abundant primary metabolites changed their state from solid to liquid when they were mixed in proper ratio.